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Venus' Mesosphere Shows Sharp Rise in Deuterium to Hydrogen Ratio
Diagram of the proposed Venus mesospheric water cycle mechanism to sustain the observed HDO and H2O VMR and HDO/H2O ratio increase with altitude.
Venus' Mesosphere Shows Sharp Rise in Deuterium to Hydrogen Ratio
by Riko Seibo
Tokyo, Japan (SPX) Aug 21, 2024

Researchers using the Solar Occultation in the Infrared (SOIR) instrument aboard the European Space Agency's Venus Express probe have observed a significant and unexpected increase in the deuterium to hydrogen ratio (HDO/H2O) in Venus' mesosphere. This discovery adds a new layer of complexity to our understanding of Venus' water history, raising questions about whether the planet may have once harbored conditions suitable for life.

Today, Venus presents a harsh environment, with surface pressures nearly 100 times those on Earth and temperatures soaring to approximately 460 C. Its thick clouds of sulfuric acid and water droplets create an extremely arid atmosphere, with most of its scant water found below the cloud layers. Despite these extreme conditions, it's believed that Venus may have once had as much water as Earth.

"Venus is often called Earth's twin due to its similar size," said Hiroki Karyu, a researcher at Tohoku University. "Despite the similarities between the two planets, it has evolved differently. Unlike Earth, Venus has extreme surface conditions."

By examining the amounts of H2O and its isotopologue HDO, scientists gain insights into Venus' water history. It is widely accepted that Venus and Earth began with a similar HDO/H2O ratio. However, the current ratio in Venus' lower atmosphere (below 70 km) is about 120 times higher than Earth's, indicating a significant enrichment of deuterium over time. This increase is largely attributed to solar radiation breaking down water isotopologues in Venus' upper atmosphere, with lighter hydrogen atoms escaping into space more easily, causing the HDO/H2O ratio to rise.

To better understand the escape rates of hydrogen (H) and deuterium (D) into space, it is essential to measure water isotopologue concentrations at altitudes above 70 km, where sunlight can break them down. The study reveals two surprising findings: both H2O and HDO concentrations increase with altitude between 70 and 110 km, and the HDO/H2O ratio skyrockets by an order of magnitude, reaching levels over 1500 times higher than those found in Earth's oceans.

One possible explanation for these observations involves the behavior of hydrated sulfuric acid (H2SO4) aerosols. These aerosols form just above the clouds, where temperatures fall below the dew point of sulfurated water, leading to the creation of deuterium-enriched particles. As these aerosols ascend to higher altitudes, they evaporate in the warmer temperatures, releasing a greater fraction of HDO compared to H2O. The vapor then descends, continuing the cycle.

The study highlights two critical factors: the importance of altitude in determining the distribution of deuterium and hydrogen, and the impact of the increased HDO/H2O ratio on the long-term evolution of the D/H ratio. These findings suggest that altitude-dependent processes must be considered in models to accurately predict the D/H evolution on Venus. Understanding the planet's water history and potential habitability could provide crucial insights into preventing Earth from following a similar path as its "twin."

Research Report:Unexpected increase of the deuterium to hydrogen ratio in the Venus mesosphere

Related Links
Tohoku University
Venus Express News and Venusian Science

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