Power at sea: towards high-performance seawater batteries

Lithium-ion batteries have taken the world by storm thanks to their remarkable properties. However, the scarcity and high cost of lithium has led researchers to look for alternative types of rechargeable batteries made using more abundant materials, such as sodium. One particularly promising type of sodium-based battery is seawater batteries (SWBs), which use seawater as the cathode.

Though SWBs are environmentally benign and naturally firesafe, the development of high-performance anode materials at a reasonable cost remains a major bottleneck that prevents commercialization. Traditional carbon-based materials are an attractive and cost-efficient option, but they have to be co-doped with multiple elements, such as nitrogen (N) and sulfur (S), to boost their performance up to par. Unfortunately, currently known synthesis routes for co-doping are complex, potentially dangerous, and don't even yield acceptable doping levels.

In a recent study, a team of scientists from Korea Maritime and Ocean University led by Associate Professor Jun Kang have found a way out of this conundrum. Their paper, which was made available online on December 22, 2021 and published in Volume 189 of Carbon on April 15, 2022, describes a novel synthesis route to obtain N/S co-doped carbon for SWB anodes.

Termed 'plasma in liquid,' their procedure involves preparing a mixture of precursors containing carbon, N, and S and discharging plasma into the solution. The result is a material with high doping levels of N and S with a structural backbone of carbon black. As proved through various experiments, this material showed great potential for SWBs, as Dr. Kang remarks: "The co-doped anode material we prepared exhibited remarkable electrochemical performance in SWBs, with a cycling life of more than 1500 cycles at a current density of 10 A/g."

The potential maritime applications of SWBs are many, since they can be safely operated while completely submerged in seawater. They can be used to supply emergency power in coastal nuclear power plants, which is difficult when using conventional diesel generators in the event of a disastrous tsunami. Additionally, they can be installed on buoys to aid in navigation and fishing. Perhaps most importantly, SWBs could be literally life-saving, as Dr. Kang explains: "SWBs can be installed as a power source for salvage equipment on passenger ships. They would not only supply a higher energy density than conventional primary batteries, but also enable stable operation in water, thereby increasing survival probabilities."

Overall, this novel synthesis method for co-doped carbon anodes might just be the answer we need to make SWBs reach new heights!

Research Report: Facile in situ synthesis of dual-heteroatom-doped high-rate capability carbon anode for rechargeable seawater-batteries

Related Links
Korea Maritime and Ocean University
Powering The World in the 21st Century at Energy-Daily.com

Tweet

Thanks for being there;
We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain.

With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords.

Our news coverage takes time and effort to publish 365 days a year.

If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.

SpaceDaily Monthly Supporter
$5+ Billed Monthly

paypal only

SpaceDaily Contributor
$5 Billed Once

credit card or paypal

Encapsulation as a method for preventing degradation in Li-air batteries
Boston MA (SPX) Jan 21, 2022
Lithium-air batteries were thought promising in the 1970s as a potential power source for electric vehicles, offering energy densities that rival gasoline and significantly surpass conventional lithium-ion batteries. However, scientists over the last few decades have been unable to overcome challenges to practical application of this technology, including reversible charging and low cyclability that results in battery degradation over few uses. A research team from MI ... read more