New light on making two-dimensional polymers

An international research team led by members from the Technical University of Munich, the Deutsches Museum, Munich, and the Swedish Linkoping University has developed a method to manufacture two-dimensional polymers with the thickness of a single molecule. The polymers are formed on a surface by the action of light. The discovery paves the way to new ultrathin and functional materials.

The quest for new two-dimensional materials has rapidly intensified after the discovery of graphene - a supermaterial whose excellent properties include high conductivity and strength, making it incredibly versatile.

Two main approaches are used to create ultrathin materials. In the first, a continuous layer of molecules or atoms is "peeled off" from the bulk of the material. Graphene is an example of such a material.

The other approach, in contrast, involves the construction of the material molecule-by-molecule by producing bonds between the molecules in various ways. The problem is that the materials are often small, fragile and contain many defects. This limits the potential areas of application.

Self organization and photopolymerisation produce new 2D-material
An international research team with members from the Technical University of Munich, the Deutsches Museum and Linkoping University, among others, has now developed a new method to manufacture two-dimensional polymers. The discovery makes it possible to develop new ultrathin functional materials with highly defined and regular crystalline structures.

The manufacture, or polymerisation, of the material takes place in two steps. The researchers use a molecule known as "fantrip". "Fantrip" is a contraction of "fluorinated anthracene triptycene". This molecule is a merger of two different hydrocarbons - anthracene and triptycene. The specific properties of fantrip cause the molecules to spontaneously arrange themselves into a pattern when they are placed onto a graphite surface covered with an alkane. This process is known as "self-organization".

The next step is the photopolymerisation itself, when the pattern is to be fixed with the aid of light. The molecules are illuminated by a violet laser that excites the electrons in the outermost electron shell. This causes strong and durable covalent bonds to form between the molecules.

The result is a porous two-dimensional polymer, half a nanometre thick, consisting of several hundred thousand molecules identically linked, in other words, a material with nearly perfect order, right down to the atomic level.

Simulations confirm the assigned structures
Since the photopolymerisation is carried out on a surface of solid graphite, it is possible to follow the process on the molecular scale using scanning tunnelling microscopy. This shows the newly formed bonds in a persistent network. In order to confirm the structure assignment, the research group led by Jonas Bjork has simulated the appearance of the molecular networks under the microscope at different stages of the reaction.

Jonas Bjork is assistant professor in the Materials Design Division at the Department of Physics, Chemistry and Biology at Linkoping University. He has used high-performance computing resources at the National Supercomputer Centre in Linkoping to validate the experiments and understand the key factors that make the method successful.

"We see that the simulations agree well with reality down to the tiniest detail, and we can also understand why our specific system gives such useful results. The next step of the research will be to see whether the method can be used to link other molecules for new two-dimensional and functional materials. By improving the method, we will also be able to control and tailor the type of ultrathin materials we aim to manufacture", says Jonas Bjork.

Fixing self-organized molecules with light
"Creating covalent bonds between molecules requires a lot of energy. The most common way of supplying energy is to raise the temperature, but this also causes the molecules to start moving. So it won't work with self-organized molecules, since the pattern would blurr. Using light to create covalent bonds preserves the pattern and fixes it precisely as we want it", says Markus Lackinger, research group leader at the Deutsches Museum and Technical University of Munich.

The polymerisation takes place in a vacuum, which ensures that the material is not contaminated. However, the final two-dimensional polymer film is also stable under atmospheric conditions, which is an advantage for future applications. Markus Lackinger believes that the material will find many conceivable applications.

"The most obvious application is to use the material as filter or membrane, but applications that we have no idea of at the moment in entirely different contexts may appear on the horizon, also by chance. This is why basic research is so exciting", says Markus Lackinger.

Research paper

Related Links
Technical University Of Munich
Stellar Chemistry, The Universe And All Within It

Tweet

Thanks for being there;
We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain.

With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords.

Our news coverage takes time and effort to publish 365 days a year.

If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.

SpaceDaily Monthly Supporter
$5+ Billed Monthly

paypal only

SpaceDaily Contributor
$5 Billed Once

credit card or paypal

UMD team demonstrates swarm of photons that somersault in lockstep
College Park MD (SPX) Jun 04, 2021
Spinning or rotating objects are commonplace, from toy tops, fidget spinners, and figure skaters to water circling a drain, tornadoes, and hurricanes. In physics, there are two kinds of rotational motion: spin and orbital. Earth's motion in our solar system illustrates these; the daily 360-degree rotation of Earth around its own axis is spin rotation, while Earth's yearly trip around the sun is orbital rotation. The quantity in physics defined to describe such motion is angular momentum (AM) ... read more