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![]() by Staff Writers Oak Ridge TN (SPX) May 22, 2018
Researchers at the Department of Energy's Oak Ridge National Laboratory made the first observations of waves of atomic rearrangements, known as phasons, propagating supersonically through a vibrating crystal lattice - a discovery that may dramatically improve heat transport in insulators and enable new strategies for heat management in future electronics devices. "The discovery gives you a different way to control the flow of heat," said lead author Michael Manley of the paper published in Nature Communications. "It provides a shortcut through the material - a way to send the energy of pure atomic motion at a speed that's higher than you can with phonons [atomic vibrations]. This shortcut may open possibilities in heat management of nanoscale materials. Imagine the possibility of a thermal circuit breaker, for example." The scientists used neutron scattering to measure phasons with velocities about 2.8 times and about 4.3 times faster than the natural "speed limits" of longitudinal and transverse acoustic waves, respectively. "We didn't expect them to be going that fast without [fading]," Manley said. Insulators are necessary in electronic devices to prevent short circuits; but without free electrons, thermal transport is limited to the energy of atomic motion. Hence, understanding the transport of heat by atomic motion in insulators is important. The researchers scattered neutrons in fresnoite, a crystalline mineral so named because it was first found in Fresno, California. It is promising for sensor applications through its piezoelectric property, which allows it to turn mechanical stress into electrical fields. Fresnoite has a flexible framework structure that develops a competing order in the structure that does not match the underlying crystal order, like an overlay of mismatched tiles. Phasons are excitations associated with atomic rearrangements in the crystal that change the phase of waves describing the mismatch in the structure. Phase differences accumulate in a lattice of wrinkles - called solitons. Solitons are solitary waves that propagate with little loss of energy and retain their shape. They can also warp the local environment in a way that allows them to travel faster than sound. "The soliton is a very deformed region in the crystal where the displacements of the atoms are large and the force-displacement relationship is no longer linear," Manley said. "The material stiffness is locally enhanced within the soliton, leading to a faster energy transfer." Raffi Sahul of Meggitt Sensing Systems of Irvine, California, grew a single crystal of fresnoite and sent it to ORNL for neutron scattering experiments that Manley conceived to characterize how energy moved through the crystal. "Neutrons are the best way to study this because their wavelengths and energies are in a sense matched to the atomic vibrations," Manley said. Manley performed measurements with Paul Stonaha, Doug Abernathy and John Budai using time-of-?ight neutron scattering at the Spallation Neutron Source, and with Stonaha, Songxue Chi, and Raphael Hermann using triple-axis neutron scattering at the High Flux Isotope Reactor. At SNS, the scientists started with a pulsed source of neutrons of different energies and used the ARCS instrument, which selects neutrons in a narrow energy range and scatters them off a sample so detectors can map the energy and momentum transfer over a wide range. "The large measurement area was important to this study because the features weren't where you would normally expect them to be," said Abernathy. "This gives the neutron measurements a great chance to determine the velocities of the propagating phasons, calculated from the slope of their dispersion curves." Dispersion is the relationship between the wavelength and the energy that characterizes a propagating wave. "Once the SNS measurements told us where to look, we used triple-axis spectrometry at HFIR, which provided a constant flux of neutrons, to focus on that one point," Manley said. "A unique thing about Oak Ridge National Laboratory is that we have both a world-class spallation source and a world-class reactor source for neutron research. We can go back and forth between facilities and really get a comprehensive view of things." Next the researchers will explore other crystals that, like fresnoite, can rotate phasons. Strain applied with an electric field may be able to change the rotation. Changes in temperature may vary properties too. The title of the paper is "Supersonic propagation of lattice energy by phasons in fresnoite."
![]() ![]() Dutch firm ASML perfecting 'microchip shrink' for tech giants Veldhoven, Netherlands (AFP) May 13, 2018 They call it "the shrink" - it's the challenge of how to pack more circuits onto the microchips which power everything from our phones to our computers, even our coffee machines. And pushing the boundaries of this technology is Dutch company ASML, which since its foundation in 1984 has quietly become a world leader in the semiconductor business. "There is more power in your smartphone today than was used to put man on the moon," says ASML's chief operating officer Frederic Schneider-Maunoury, a ... read more
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